Pregled bibliografske jedinice broj: 494156
Transformation of Calcium Oxalate Hydrates
Transformation of Calcium Oxalate Hydrates // Journal of crystal growth, 74 (1986), 2; 399-408 doi:10.1016/0022-0248(86)90131-4 (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 494156 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Transformation of Calcium Oxalate Hydrates
Autori
Brečević, Ljerka ; Škrtić, Drago ; Garside, John
Izvornik
Journal of crystal growth (0022-0248) 74
(1986), 2;
399-408
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
calcium oxalate hydrates ; transformation ; kinetics
Sažetak
The transformation kinetics of calcium oxalate trihydrate and calcium oxalate dihydrate to the thermodynamically stable monohydrate have been studied in batch precipitation systems. A combination of size distribution measurements, optical microscopy, X-ray diffraction and thermogravimetric analysis were used to characterise the processes involved. The transformation appears to be a solution mediated process in which dissolution of the unstable phases is followed by growth of the monohydrate ; corresponding dissolution and growth rates have been determined. The distribution of hydrates in the initial stages of the precipitation was very sensitive to the mixing process ; for example the use of a magnetic stirrer produced a different distribution to that formed with a propeller agitator.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Ustanove:
Institut "Ruđer Bošković", Zagreb
Citiraj ovu publikaciju:
Časopis indeksira:
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus