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Pregled bibliografske jedinice broj: 472668

Electronic structure and stability of some silicon compounds

Novak, Igor; Abu-Izneid, Tareq; Kovač, Branka
Electronic structure and stability of some silicon compounds // Chemical physics letters, 491 (2010), 4-6; 136-139 doi:10.1016/j.cplett.2010.03.079 (međunarodna recenzija, članak, znanstveni)

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Naslov
Electronic structure and stability of some silicon compounds

Autori
Novak, Igor ; Abu-Izneid, Tareq ; Kovač, Branka

Izvornik
Chemical physics letters (0009-2614) 491 (2010), 4-6; 136-139

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
photoelectron spectroscopy ; electronic structure ; silicon compounds

Sažetak
The electronic structures of N, 1, 3-tris(1, 1-dimethylethyl)-cyclodisilazan-2-amine (I) and 2, 3, 5, 5-tetrakis(trimethylsilyl)cyclopentadiene (II) have been investigated by HeI and HeII UV photoelectron spectroscopy(UPS) and quantum chemical calculations. We discuss the influence of substituent effects on their electronic structure and thermodynamic stability. Our study shows that trimethylsilyl substituents have strong influence on the electronic structure of cyclopentadiene via inductive effect. Their influence on thermodynamic stability is also pronounced. In substituted cyclodisilazanes hyperconjugative influence of alkylsilyl groups was shown to cause relative thermodynamic stabilization of the cyclodisilazane system.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA

Projekti:
098-0982915-2945 - Spektroskopija, kemijska svojstva i reakcije biološki aktivnih molekula (Kovač, Branka, MZOS ) ( CroRIS)

Ustanove:
Institut "Ruđer Bošković", Zagreb

Profili:

Avatar Url Igor Novak (autor)

Avatar Url Branka Kovač (autor)

Poveznice na cjeloviti tekst rada:

doi www.sciencedirect.com doi.org

Citiraj ovu publikaciju:

Novak, Igor; Abu-Izneid, Tareq; Kovač, Branka
Electronic structure and stability of some silicon compounds // Chemical physics letters, 491 (2010), 4-6; 136-139 doi:10.1016/j.cplett.2010.03.079 (međunarodna recenzija, članak, znanstveni)
Novak, I., Abu-Izneid, T. & Kovač, B. (2010) Electronic structure and stability of some silicon compounds. Chemical physics letters, 491 (4-6), 136-139 doi:10.1016/j.cplett.2010.03.079.
@article{article, author = {Novak, Igor and Abu-Izneid, Tareq and Kova\v{c}, Branka}, year = {2010}, pages = {136-139}, DOI = {10.1016/j.cplett.2010.03.079}, keywords = {photoelectron spectroscopy, electronic structure, silicon compounds}, journal = {Chemical physics letters}, doi = {10.1016/j.cplett.2010.03.079}, volume = {491}, number = {4-6}, issn = {0009-2614}, title = {Electronic structure and stability of some silicon compounds}, keyword = {photoelectron spectroscopy, electronic structure, silicon compounds} }
@article{article, author = {Novak, Igor and Abu-Izneid, Tareq and Kova\v{c}, Branka}, year = {2010}, pages = {136-139}, DOI = {10.1016/j.cplett.2010.03.079}, keywords = {photoelectron spectroscopy, electronic structure, silicon compounds}, journal = {Chemical physics letters}, doi = {10.1016/j.cplett.2010.03.079}, volume = {491}, number = {4-6}, issn = {0009-2614}, title = {Electronic structure and stability of some silicon compounds}, keyword = {photoelectron spectroscopy, electronic structure, silicon compounds} }

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus

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