Pregled bibliografske jedinice broj: 472050
Leaving Group Property of Dimethyl Sulfide
Leaving Group Property of Dimethyl Sulfide // Journal of organic chemistry, 75 (2010), 11; 3851-3854 doi:10.1021/jo100327c (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 472050 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Leaving Group Property of Dimethyl Sulfide
Autori
Jurić, Sandra ; Denegri, Bernard ; Kronja, Olga
Izvornik
Journal of organic chemistry (0022-3263) 75
(2010), 11;
3851-3854
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
benzhydryl dimethyl sulfonates; dimethyl sulfide; kinetics; LFER; nucleofugality; solvolysis
Sažetak
The LFER equation log k = sf (Ef + Nf) was used to derive the nucleofuge specific parameters (Nf and sf) for dimethyl sulfide in the series of aqueous alcohols, using the SN1 solvolysis rate constants obtained for X-substituted benzhydryl dimethyl sulfonates 1-5. The slope parameters (sf) are practically independent on the solvent used, while Nf parameters slightly decrease as the polarity of the solvent increases.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Projekti:
006-0982933-2963 - Skala stabilnosti karbokationa, njihove strukture i biomimetska pregrađivanja (Kronja, Olga, MZOS ) ( CroRIS)
Ustanove:
Farmaceutsko-biokemijski fakultet, Zagreb
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
- MEDLINE
