Pregled bibliografske jedinice broj: 469595
Electrochemical synthesis and crystal structure of a penta-coordinated silver(II) macrocyclic complex
Electrochemical synthesis and crystal structure of a penta-coordinated silver(II) macrocyclic complex // Inorganica Chimica Acta, 362 (2009), 11; 4009-4012 doi:10.1016/j.ica.2009.05.050 (međunarodna recenzija, članak, znanstveni)
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Naslov
Electrochemical synthesis and crystal structure of a penta-coordinated silver(II) macrocyclic complex
Autori
Kandaiah, Sakthivel ; Halasz, Ivan ; Dinnebier, Robert E. ; Jansen Martin
Izvornik
Inorganica Chimica Acta (0020-1693) 362
(2009), 11;
4009-4012
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
Silver; Higher oxidation state; Tetramethyltetraazacyclotetradecane; Electrochemical synthesis; Solvent coordination; hexafluorophosphate
Sažetak
We present the electrochemical synthesis by galvanostatic electro-oxidation method and single crystal structure determination of a complex of silver(II) with a macrocyclic N donor ligand crystallized with hexafluorophosphate anions. The crystal structure analysis showed a penta-coordinated environment of silver(II) and displacement of the metal centre from the rectangular planar configuration of the macrocyclic N donor which is due to axial coordination by a solvent acetonitrile molecule. Both PF6- anions were modelled with two-fold disorder.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
