Pregled bibliografske jedinice broj: 431575
Ferrocene compounds XVII. Synthesis of some ferrocenyl carbinols, ethers, and ureas
Ferrocene compounds XVII. Synthesis of some ferrocenyl carbinols, ethers, and ureas // Journal of Organometallic Chemistry, 384 (1990), 147-153 (međunarodna recenzija, članak, znanstveni)
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Naslov
Ferrocene compounds XVII. Synthesis of some ferrocenyl carbinols, ethers, and ureas
Autori
Kovač, Spomenka ; Rapić, Vladimir
Izvornik
Journal of Organometallic Chemistry (0022-328X) 384
(1990);
147-153
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
Aroylferrocenes; Condensations; Carbinols
Sažetak
Reduction of several aroylferrocenes (1) with sodium borohydride in methanol has given 20-64% yields of alpha-arylgferrocenenethanols (2). Reaction of ferrocene with benzaldehyde in sulphuric acid at -10C gave alpha-phenylferrocenemethanol (2b) (29%) and bis(phenyl(ferrocenyl)methyl)ether (3a) (35%), and similar reaction with tolualdehyde gave the corresponding carbinol "e (21%) and the sym-ether 3b (42%). Condensations of the carbinols with methylisocyanate gave N-(aryl(ferrocenyl)methyl)-N, N'-dimethylureas (4) in 22-61% yields.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Ustanove:
Prehrambeno-biotehnološki fakultet, Zagreb,
Prehrambeno-tehnološki fakultet, Osijek
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus