Pregled bibliografske jedinice broj: 422759
Extraction and Complex Formation of Thorium(IV) with 3-Hydroxy-2-Methyl-1-(4-Tolyl)-4-Pyridone
Extraction and Complex Formation of Thorium(IV) with 3-Hydroxy-2-Methyl-1-(4-Tolyl)-4-Pyridone // Journal of inorganic & nuclear chemistry, 40 (1978), 335-338 (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 422759 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Extraction and Complex Formation of Thorium(IV) with 3-Hydroxy-2-Methyl-1-(4-Tolyl)-4-Pyridone
Autori
Tamhina, Biserka ; Gojmerac, Astrid ; Herak, Marko
Izvornik
Journal of inorganic & nuclear chemistry (0022-1902) 40
(1978);
335-338
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
extraction ; thorium(IV) ; 4-pyridone derivatives
Sažetak
The extraction of thorium(IV) from aqueous hydrochloric and nitric acid solution by 3-Hydroxy-2-Methyl-1-(4-Tolyl)-4-Pyridone (HY) dissolved in chloroform has been studied. Thorium(IV) is quantitatively extracted at pH>3, 8 from the hydrochloric acid solution containing an excess of chloride ions, and at pH > 2, 5 from nitric acid solution containing an excess of nitrate ions. Extracted thorium can be quantitatively stripped with 1M hydrochloric or nitric acid. The sepoaration of protactinium from thorium is described. The mechanism of thorium extraction has been studied. The composition of the extractable thorium complexes depends on the HY-Th concentration ratio and on the kind of mineral acid present in the aqueous phase. The solid complex ThCl3YHY was isolated and its composition verified by chemical analysis.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Ustanove:
Prirodoslovno-matematički fakultet, Zagreb
Citiraj ovu publikaciju:
Časopis indeksira:
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
