Pregled bibliografske jedinice broj: 396329
Asimmetric reaction of Paternò ; -Buchi on furan and benzoin derivatives
Asimmetric reaction of Paternò ; -Buchi on furan and benzoin derivatives // TRAMECH 2004
Marakeš, Maroko, 2004. (poster, nije recenziran, sažetak, znanstveni)
CROSBI ID: 396329 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Asimmetric reaction of Paternò ; -Buchi on furan and benzoin derivatives
Autori
D'Auria, Maurizio ; Emanuele, Lucia ; Racioppi, Rocco
Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni
Skup
TRAMECH 2004
Mjesto i datum
Marakeš, Maroko, 23.11.2004. - 27.11.2004
Vrsta sudjelovanja
Poster
Vrsta recenzije
Nije recenziran
Ključne riječi
photochemistry; furan; benzoin; benzofuran; Paterno-Buchi reaction
Sažetak
The reaction of benzoin, 4, 4'-dimethoxybenzoin and benzoin ethyl ether with furan gave the corresponding adduct with high diastereoselectivity (71-100%). The diastereoselectivity was explained considering the relative stability of the biradical intermediates. Benzofuran reacts with (S)-1-methylpropylbenzoylformate to give the corresponding adduct with de = 58%. The diastereoselectivity was explained considering the relative stability of the biradical intermediates.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
