Pregled bibliografske jedinice broj: 396324
Asimmetric Paternò ; -Buchi on furan derivatives: the hydroxy directing effect in 2-furylmethanols
Asimmetric Paternò ; -Buchi on furan derivatives: the hydroxy directing effect in 2-furylmethanols // TRAMECH 2004
Marakeš, Maroko, 2004. (poster, nije recenziran, sažetak, znanstveni)
CROSBI ID: 396324 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Asimmetric Paternò ; -Buchi on furan derivatives: the hydroxy directing effect in 2-furylmethanols
Autori
D'Auria, Maurizio ; Emanuele, Lucia ; Racioppi, Rocco
Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni
Skup
TRAMECH 2004
Mjesto i datum
Marakeš, Maroko, 23.11.2004. - 27.11.2004
Vrsta sudjelovanja
Poster
Vrsta recenzije
Nije recenziran
Ključne riječi
cycloaddition; allylic alcohols; stereoselectivity
Sažetak
The stereoselectivity of the photochemical reaction between acetophenone and 2, 2, 5-trimethyl-4-hexen-3-ol was explained on the basis of a DFT study. Conformational analysis of the starting material showed that two conformations were the most stable ones. Assuming that the attack of the excited carbonyl group occurred on the same side of the hydroxy group (due to hydrogen bond or to the formation of a complex), the possible conformations of the biradical intermediate was examined. Only the precursors of the threo stereoisomer was obtained in agreement with experimental results.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
