Pregled bibliografske jedinice broj: 395621
Surface charge of gibbsite samples – 2 Questions and possible answers
Surface charge of gibbsite samples – 2 Questions and possible answers // 8th Keele Meeting on Aluminium, The Natural History of Aluminium from Non-Selection to Natural Selection / Christopher Exley, Marek Batysta, Luboš Borůvka, Ondřej Drábek, Karel Němeček (ur.).
Prag: Czech University of Life Sciences Prague (CZU), 2009. str. 1-1 (poster, međunarodna recenzija, sažetak, znanstveni)
CROSBI ID: 395621 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Surface charge of gibbsite samples – 2 Questions and possible answers
Autori
Lefevre, Gregory ; Fedoroff, Michel ; Adeloka ; Lützenkirchen, Johannes ; Rabung, Thomas ; Huittinen, Nina ; Kupcik, Tom ; Geckeis, Horst ; Preočanin, Tajana ; Azad, Mehri ; Schäfer, Bastian ; Nirschl, Hermann ; Rosenqvist, Jörgen ; Sjöberg, Staffan
Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni
Izvornik
8th Keele Meeting on Aluminium, The Natural History of Aluminium from Non-Selection to Natural Selection
/ Christopher Exley, Marek Batysta, Luboš Borůvka, Ondřej Drábek, Karel Němeček - Prag : Czech University of Life Sciences Prague (CZU), 2009, 1-1
ISBN
978-80-213-1910-3
Skup
8th Keele Meeting on Aluminium, The Natural History of Aluminium from Non-Selection to Natural Selection
Mjesto i datum
Třešť, Češka Republika, 21.02.2009. - 25.02.2009
Vrsta sudjelovanja
Poster
Vrsta recenzije
Međunarodna recenzija
Ključne riječi
α -Al2O3; electical interfacial layer; interfacial charging; MUSIC model; colloid adsorption
Sažetak
We discuss the interfacial behaviour of α -Al2O3 basal planes in electrolyte solutions. The perfect, O-terminated, hydroxylated surface should consist of only doubly-coordinated hydroxyls (DCHs), i.e. a well-suited surface for the understanding of interfacial charging processes. Based on the popular MUSIC model these DCHs are not proton active over a wide pH range. The point of zero charge is expected at pH 6 and the surface potential should exhibit a plateau between pH 4.5 and 7.5. A wide range of data related to the interfacial charging of this plane have been obtained with various techniques including non-linear optics, atomic force microscopy, streaming potential and current measurements, colloid adsorption and contact angle titration. Most of these data show sharp points of zero charge below pH 5. In order to explain why the charging of these “ ideal” model systems is very different from those of corresponding particles we discuss the available data with respect to water ion adsorption.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Projekti:
119-1191342-2961 - Fizikalna kemija koloida i međupovršina (Kallay, Nikola, MZOS ) ( CroRIS)
Ustanove:
Prirodoslovno-matematički fakultet, Zagreb
Profili:
Tajana Begović
(autor)