Pregled bibliografske jedinice broj: 392602
Polyoxometalates and vanadium alkoxides : Electronic structure and properties
Polyoxometalates and vanadium alkoxides : Electronic structure and properties // Chemical physics letters, 474 (2009), 1-3; 33-35 doi:10.1016/j.cplett.2009.04.027 (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 392602 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Polyoxometalates and vanadium alkoxides : Electronic structure and properties
Autori
Novak, Igor ; Kovač, Branka
Izvornik
Chemical physics letters (0009-2614) 474
(2009), 1-3;
33-35
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
HeI/HeII photoelectron spectra ; vanadium alkoxides ; electronic structure
Sažetak
The HeI/HeII photoelectron spectra of oxovanadium triethoxide (I) and oxovanadium triisopropoxide (II)are reported for the first time. We have observed significant differences in the electronic structure of the title molecules compared to their titanium analogues. Metal alkoxides (containing Mo, W, V, Nb) are precursors of polyoxometalates which are capable of supporting reversible redox reactions in the solid state. Vanadium alkoxides contain high lying occupied valence orbitals with metal character which explains the ability of their derivative polyoxometalates to become involved in reversible redox reactions.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Projekti:
098-0982915-2945 - Spektroskopija, kemijska svojstva i reakcije biološki aktivnih molekula (Kovač, Branka, MZOS ) ( CroRIS)
Ustanove:
Institut "Ruđer Bošković", Zagreb
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
