Pregled bibliografske jedinice broj: 391949
Pitfalls of the phase-shift method for determining adsorption isotherms
Pitfalls of the phase-shift method for determining adsorption isotherms // Electrochemistry communications, 11 (2009), 7; 1460-1463 doi:10.1016/j.elecom.2009.05.032 (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 391949 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Pitfalls of the phase-shift method for determining adsorption isotherms
Autori
Horvat-Radošević, Višnja ; Kvastek, Krešimir
Izvornik
Electrochemistry communications (1388-2481) 11
(2009), 7;
1460-1463
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
Phase-shift method ; EIS ; Adsorption impedance ; Adsorption isotherms
Sažetak
Pitfalls of the phase-shift method for determining adsorption isotherms in the case of two-step Faradaic reactions involving adsorption at transition metals (alloys)/aqueous solution interfaces are discussed following the recent publication of the paper [J.Y. Chun, J.H. Chun, Electrochem. Commun., 11(2009)744]. It is shown how the pitfalls of the method are generated by improper analysis of impedance data resulting in at least disputable values characterizing adsorption isotherms (equilibrium constant, K, standard free energy, and interaction parameter between adsorbed species, g).
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Projekti:
098-0982904-2905 - Elektroaktivni filmovi za ekološki prihvatljivu konverziju i pohranu energije (Horvat-Radošević, Višnja, MZOS ) ( CroRIS)
Ustanove:
Institut "Ruđer Bošković", Zagreb
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
