Pregled bibliografske jedinice broj: 386268
Intramolecular, g C-H vs. Olefin Cycloaddition in 4- Methylene-2-adamantylidene and 8-Methylene-2-noradamantylidene
Intramolecular, g C-H vs. Olefin Cycloaddition in 4- Methylene-2-adamantylidene and 8-Methylene-2-noradamantylidene // Journal of the Chemical Society. Chemical communications, 24 (1985), 1830-1831 doi:10.1039/C39850001830 (međunarodna recenzija, članak, znanstveni)
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Naslov
Intramolecular, g C-H vs. Olefin Cycloaddition in 4- Methylene-2-adamantylidene and 8-Methylene-2-noradamantylidene
(INTRAMOLECULAR GAMMA-C-H INSERTION VS OLEFIN CYCLOADDITION IN 4-METHYLENE-2-ADAMANTYLIDENE AND 8-METHYLENE-2-NORADAMANTYLIDENE)
Autori
Majerski, Zdenko ; Hameršak, Zdenko ; Majerski, Kata
Izvornik
Journal of the Chemical Society. Chemical communications (0022-4936) 24
(1985);
1830-1831
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
carbene ; CH-insertion ; propellane
Sažetak
8-Methylene-2-noradamantylidene inserts readily into the y C-H bond giving 6-methylene-2, 4-didehydronoradamantane rather than the olefin-cycloaddition product, while its higher homologue 4-methylene-2-adamantylidene reacts exclusively by intramolecular cycloaddition to the olefinic bond yielding 2, 4-methano-2, 4-didehydroadamantane, a [3.1 .I .]propellane.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Ustanove:
Institut "Ruđer Bošković", Zagreb
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus