Pregled bibliografske jedinice broj: 379881
A multi-technique study of gold oxidation and semiconducting properties of the compact α -oxide layer
A multi-technique study of gold oxidation and semiconducting properties of the compact α -oxide layer // Journal of Electroanalytical Chemistry, 629 (2009), 1-2; 43-49 doi:10.1016/j.jelechem.2009.01.020 (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 379881 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
A multi-technique study of gold oxidation and semiconducting properties of the compact α -oxide layer
(A multi-technique study of gold oxidation and semiconducting properties of the compact alfa-oxide layer)
Autori
Petrović, Željka ; Metikoš-Huković, Mirjana ; Babić, Ranko ; Katić, Jozefina ; Milun, Milorad
Izvornik
Journal of Electroanalytical Chemistry (1572-6657) 629
(2009), 1-2;
43-49
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
electrooxidation of gold; Underpotential Deposition (UPD) of OH radicals; semiconducting properties; electrochemical ac/dc techniques; EQCN; XPS
Sažetak
The initial stage of gold oxidation at the quartz crystal electrode in a near neutral solution was studied by using potentiostatic and potentiodynamic sweep methods. The underpotential deposition of OH radicals was the first stage of the nucleation and formation of the phase oxide Au2O3. The composition of the oxide was determined by the X-ray photoemission spectroscopy (XPS). Three-dimensional (3D) progressive nucleation occurred under diffusion control. The electronic structure of the compact alfa-oxide film and the charge distribution at the oxide layer / electrolyte interface were examined using photopotential and capacitance measurements. Anodically formed oxide film on gold was highly-doped defect semiconductor of n-type conductivity.
Izvorni jezik
Engleski
Znanstvena područja
Fizika, Kemija
POVEZANOST RADA
Projekti:
035-0352828-2840 - Elektronska i kristalna struktura poduprtih samoorganiziranih nano-sistema (Pervan, Petar, MZOS ) ( CroRIS)
125-0982904-2923 - Novi materijali i katalizatori za održive tehnologije (Metikoš-Huković, Mirjana, MZOS ) ( CroRIS)
Ustanove:
Institut za fiziku, Zagreb,
Fakultet kemijskog inženjerstva i tehnologije, Zagreb
Profili:
Milorad Milun
(autor)
Željka Petrović
(autor)
Mirjana Metikoš-Huković
(autor)
Jozefina Katić
(autor)
Ranko Babić
(autor)
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus