Naslov
Cathodic Stripping Voltammetry of Uracil. Experimental and Theoretical Study under Conditions of Square-Wave Voltammetry

Autori
Mirčeski, Valentin ; Skrzypek, Sławomira ; Lovrić, Milivoj

Izvornik
Electroanalysis (1040-0397) 21 (2009), 1; 87-95

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
uracil ; cathodic stripping voltammetry ; square-wave voltammetry ; mathematical modelling

Sažetak
Electrode mechanism of uracil at a hanging mercury drop electrode (HMDE) is studied under cathodic stripping square-wave voltammetric mode owing to the cathodic dissolution of a sparingly soluble compound formed between the electrode material and uracil. The experimental results can be partly explained in the light of the recent theory for cathodic stripping processes of insoluble salts under conditions of square-wave voltammetry. It is established that the electrode reaction is complicated by attractive interactions between the deposited species of the insoluble compound. To elucidate completely the electrode mechanism a novel theoretical model is developed considering adsorption of the reacting analyte and lateral interactions between species of the insoluble compound. With the help of numerical simulations the effect of interactions is studied in detail, emphasizing the properties of the response that can be used as diagnostic criteria for recognition of the type of interaction forces. The theoretically predicted voltammetric properties agree well with the experimental results enabling clarification of the complex electrode mechanism of uracil at HMDE.

Izvorni jezik
Engleski

Znanstvena područja
Kemija

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