Pregled bibliografske jedinice broj: 374839
Highly Enantioselective Aziridination of N-Protected Imines : Comparison of the Phosphazene EtP2 and Sodium Hydride as Bases
Highly Enantioselective Aziridination of N-Protected Imines : Comparison of the Phosphazene EtP2 and Sodium Hydride as Bases // Synlett, 2008 (2008), 20; 3149-3152 doi:10.1055/s-0028-1087367 (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 374839 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Highly Enantioselective Aziridination of N-Protected Imines : Comparison of the Phosphazene EtP2 and Sodium Hydride as Bases
Autori
Stipetić, Irena ; Roje, Marin ; Hameršak, Zdenko
Izvornik
Synlett (0936-5214) 2008
(2008), 20;
3149-3152
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
asymmetric synthesis ; aziridines ; enantioselectivity ; imine ; ylide
Sažetak
Asymmetric synthesis of 2, 3-disubstituted N-Boc, N-SES, and N-Ts aziridines starting from N-protected imines, using sulfonium salt derived from Eliel’ s oxathiane, is reported. Sodium hydride was successfully used as a substitute for the phosphazene base EtP2 without any loss of yield, enantioselectivity, or diastereoselectivity.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Projekti:
098-0982933-2908 - Kiralni građevni blokovi za biološki aktivne molekule. Sinteza i reaktivnost (Hameršak, Zdenko, MZOS ) ( CroRIS)
Ustanove:
Institut "Ruđer Bošković", Zagreb
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
