Pregled bibliografske jedinice broj: 37122
The effect of temperature and pressure on the optical absorption edge in Cu6PS5X (X = Cl, Br, I) crystals
The effect of temperature and pressure on the optical absorption edge in Cu6PS5X (X = Cl, Br, I) crystals // Journal of physics and chemistry of solids, 60 (1999), 12; 1897-1904 doi:10.1016/S0022-3697(99)00220-6 (međunarodna recenzija, članak, znanstveni)
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Naslov
The effect of temperature and pressure on the optical absorption edge in Cu6PS5X (X = Cl, Br, I) crystals
Autori
Studenyak, Igor P. ; Kranjčec, Mladen ; Kovacs, G.S. ; Panko, V.V. ; Desnica, Dunja Ida ; Slivka, A.G. ; Guranich, P.P.
Izvornik
Journal of physics and chemistry of solids (0022-3697) 60
(1999), 12;
1897-1904
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
superionic ferroelastics
Sažetak
The absorption edge of monocrystalline Cu6PS5X (X = Cl, Br, I) superionic ferroelastics was studied in the 77-303 K temperature range and the mechanisms of exciton-phonon interactions resulting in exponential absorption edges and Urbach tails were analysed. Various types of disordering, affecting the optical absorption tails, were studied. The investigation of the influence of hydrostatic pressure (up to 400 MPa) on optical transitions of Cu6PS5X at 295 K revealed that the increase of pressure causes an increase of the optical pseudogap as well as the increase of the slope of the absorption edge indicating pronounced ordering in most disordered crystals. Data obtained from the pressure studies confirmed the predominant contribution of exciton-phonon interaction to the temperature shift of the Urbach absorption edge.
Izvorni jezik
Engleski
Znanstvena područja
Fizika
POVEZANOST RADA
Ustanove:
Institut "Ruđer Bošković", Zagreb,
Prirodoslovno-matematički fakultet, Zagreb
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus