Naslov
Solid state vs. solution photochemistry of N-(2-adamantyl)phthalimide

Autori
Basaric, Nikola ; Horvat, Margareta ; Mlinarić-Majerski, Kata ; Neudörfl, Jörg ; Griesbeck, G. Axel

Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni

Izvornik
XXIInd IUPAC Symposium on Photochemistry / - Gothenburg, 2008, 405-405

Skup
XXIInd IUPAC Symposium on Photochemistry

Mjesto i datum
Göteborg, Švedska, 28.07.2008. - 01.08.2008

Vrsta sudjelovanja
Poster

Vrsta recenzije
Međunarodna recenzija

Ključne riječi
adamantane; H-abstraction; phthalimide; photochemistry

Sažetak
Photochemistry in the solid state has attracted considerable attention in last decades. The main interest for caring out photoreactions in the solid state is stereoselectivity which can not be attained in the solution phase. Besides, crystals provide ideal environments for studying the structure-reactivity relationship. In the scope of our research on the photochemistry of adamantane-phthalimides we turned our attention to photoreactions in the solid state. We discovered that photoreaction of N-(2-adamantyl)phthalimide in solution gives products with exo-alcohol prevailing in the photolysis mixture. On the other hand in the solid state, photochemical reaction is selective giving the endo-alcohol. The reason for the different selectivity of the reaction in the solution and the solid state will be discussed.

Izvorni jezik
Engleski

Znanstvena područja
Kemija

POVEZANOST RADA