Naslov
Phase behavior and miscibility in polymer blends containing styrene and 2, 6-dimethyl-1, 4-phenylene oxide derivatives

Autori
Vuković, Radivoje ; Bogdanić, Grozdana ; Karasz, E. Frank ; MacKnight, J. William

Izvornik
Journal of physical and chemical reference data (0047-2689) 28 (1999), 3; 851-868

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
mean-field model; miscibility; polymer blends; polystyrene; styrene derivative polymers; poly(2; 6-dimethyl-1; 4-phenylene oxide); sulfonylated poly(2; 6-dimethyl-1; 4-phenylene oxide); segmental interaction parameters

Sažetak
This article presents a comprehensive and systematc survey of miscibility in binarymixtures of polymers and copolymers based on styrene, on 2, 6-dimethyl-1, 4-phenylene oxide, and on their derivatives. Certain other systems based on methacrylate, acrylonitrile and maleic anhydride-containing polymers are also included to complete the analysis. Experimental and theoretical studies of miscibility and phase behaviors of homopolymer/homopolymer, homopolymer/copolymer and copolymer/copolymer blends are analyzed. A mean-field model is employed to correlate and predict miscibility in new systems. The model is also used to account for the different phenomena governing the miscibility/immiscibility behavior, with special reference to the influence of the chemical structure of the polymers. Tables containing experimental data and related details are included for 127 polymer/polymer systems ; these tables also contain summaries of the binary phase behavior. Calculated segmental interaction parameters, together with the relevant references and recommended values are also tabulated.

Izvorni jezik
Engleski

Znanstvena područja
Kemija

POVEZANOST RADA