Pregled bibliografske jedinice broj: 347143
PCET in the Oxidation of Ascorbate. Dramatic Change of the Kinetic Isotope Effect on the Change in Solvent Polarity
PCET in the Oxidation of Ascorbate. Dramatic Change of the Kinetic Isotope Effect on the Change in Solvent Polarity // Tetrahedron Letters, 48 (2007), 21; 3633-3637 doi:10.1016/j.tetlet.2007.03.140 (međunarodna recenzija, članak, znanstveni)
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Naslov
PCET in the Oxidation of Ascorbate. Dramatic Change of the Kinetic Isotope Effect on the Change in Solvent Polarity
Autori
Vuina, Daniela ; Pilepić, Viktor ; Ljubas, Daniel ; Sanković, Krešimir ; Sajenko, Ivana ; Uršić, Stanko
Izvornik
Tetrahedron Letters (0040-4039) 48
(2007), 21;
3633-3637
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
proton-coupled electron transfer; kinetic isotope effects; ascorbate
Sažetak
The first step of the oxydation of ascorbate with substituted nitrosobenzenes is a proton-coupled electron transfer (PCET) reaction and the observed kinetic isotope effects in the reaction, kH2O/kD2O, change dramatically with the change in solvent polarity, in line with the known theoretical predictions.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Projekti:
006-0063082-0354 - Fizikalno kemijske interakcije biomedicinski važnih prirodnih antioksidansa (Pilepić, Viktor) ( CroRIS)
Ustanove:
Farmaceutsko-biokemijski fakultet, Zagreb
Profili:
Krešimir Sanković
(autor)
Daniela Vuina
(autor)
Viktor Pilepić
(autor)
Stanko Uršić
(autor)
Ivana Fabijanić
(autor)
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus