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Pregled bibliografske jedinice broj: 347143

PCET in the Oxidation of Ascorbate. Dramatic Change of the Kinetic Isotope Effect on the Change in Solvent Polarity


Vuina, Daniela; Pilepić, Viktor; Ljubas, Daniel; Sanković, Krešimir; Sajenko, Ivana; Uršić, Stanko
PCET in the Oxidation of Ascorbate. Dramatic Change of the Kinetic Isotope Effect on the Change in Solvent Polarity // Tetrahedron Letters, 48 (2007), 21; 3633-3637 doi:10.1016/j.tetlet.2007.03.140 (međunarodna recenzija, članak, znanstveni)


CROSBI ID: 347143 Za ispravke kontaktirajte CROSBI podršku putem web obrasca

Naslov
PCET in the Oxidation of Ascorbate. Dramatic Change of the Kinetic Isotope Effect on the Change in Solvent Polarity

Autori
Vuina, Daniela ; Pilepić, Viktor ; Ljubas, Daniel ; Sanković, Krešimir ; Sajenko, Ivana ; Uršić, Stanko

Izvornik
Tetrahedron Letters (0040-4039) 48 (2007), 21; 3633-3637

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
proton-coupled electron transfer; kinetic isotope effects; ascorbate

Sažetak
The first step of the oxydation of ascorbate with substituted nitrosobenzenes is a proton-coupled electron transfer (PCET) reaction and the observed kinetic isotope effects in the reaction, kH2O/kD2O, change dramatically with the change in solvent polarity, in line with the known theoretical predictions.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Projekti:
006-0063082-0354 - Fizikalno kemijske interakcije biomedicinski važnih prirodnih antioksidansa (Pilepić, Viktor) ( CroRIS)

Ustanove:
Farmaceutsko-biokemijski fakultet, Zagreb

Poveznice na cjeloviti tekst rada:

doi www.sciencedirect.com ac.els-cdn.com dx.doi.org

Citiraj ovu publikaciju:

Vuina, Daniela; Pilepić, Viktor; Ljubas, Daniel; Sanković, Krešimir; Sajenko, Ivana; Uršić, Stanko
PCET in the Oxidation of Ascorbate. Dramatic Change of the Kinetic Isotope Effect on the Change in Solvent Polarity // Tetrahedron Letters, 48 (2007), 21; 3633-3637 doi:10.1016/j.tetlet.2007.03.140 (međunarodna recenzija, članak, znanstveni)
Vuina, D., Pilepić, V., Ljubas, D., Sanković, K., Sajenko, I. & Uršić, S. (2007) PCET in the Oxidation of Ascorbate. Dramatic Change of the Kinetic Isotope Effect on the Change in Solvent Polarity. Tetrahedron Letters, 48 (21), 3633-3637 doi:10.1016/j.tetlet.2007.03.140.
@article{article, author = {Vuina, Daniela and Pilepi\'{c}, Viktor and Ljubas, Daniel and Sankovi\'{c}, Kre\v{s}imir and Sajenko, Ivana and Ur\v{s}i\'{c}, Stanko}, year = {2007}, pages = {3633-3637}, DOI = {10.1016/j.tetlet.2007.03.140}, keywords = {proton-coupled electron transfer, kinetic isotope effects, ascorbate}, journal = {Tetrahedron Letters}, doi = {10.1016/j.tetlet.2007.03.140}, volume = {48}, number = {21}, issn = {0040-4039}, title = {PCET in the Oxidation of Ascorbate. Dramatic Change of the Kinetic Isotope Effect on the Change in Solvent Polarity}, keyword = {proton-coupled electron transfer, kinetic isotope effects, ascorbate} }
@article{article, author = {Vuina, Daniela and Pilepi\'{c}, Viktor and Ljubas, Daniel and Sankovi\'{c}, Kre\v{s}imir and Sajenko, Ivana and Ur\v{s}i\'{c}, Stanko}, year = {2007}, pages = {3633-3637}, DOI = {10.1016/j.tetlet.2007.03.140}, keywords = {proton-coupled electron transfer, kinetic isotope effects, ascorbate}, journal = {Tetrahedron Letters}, doi = {10.1016/j.tetlet.2007.03.140}, volume = {48}, number = {21}, issn = {0040-4039}, title = {PCET in the Oxidation of Ascorbate. Dramatic Change of the Kinetic Isotope Effect on the Change in Solvent Polarity}, keyword = {proton-coupled electron transfer, kinetic isotope effects, ascorbate} }

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus


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