Pregled bibliografske jedinice broj: 323543
Boron atom as an electron density relay
Boron atom as an electron density relay // Inorganica chimica acta, 361 (2008), 5; 1520-1523 doi:10.1016/j.ica.2007.09.003 (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 323543 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Boron atom as an electron density relay
Autori
Novak, Igor ; Kovač, Branka
Izvornik
Inorganica chimica acta (0020-1693) 361
(2008), 5;
1520-1523
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
Photoelectron spectroscopy ; Boranes
Sažetak
The electronic structure of tetrapyrrolidinodiborane [(C4H8N)2B]2 has been investigated by HeI and HeII UV photoelectron spectroscopy(UPS) and DFT/OVGF calculations. Our results indicate that the title molecule has very low first ionization energy and can bereadily oxidized in solution. We estimated the magnitudes of alkyl substituent effects on nitrogen and boron atoms and the efficiency of boron atom to act as an electron density relay facilitating through-bond interactions between the nitrogen lone pairs.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Projekti:
098-0982915-2945 - Spektroskopija, kemijska svojstva i reakcije biološki aktivnih molekula (Kovač, Branka, MZOS ) ( CroRIS)
Ustanove:
Institut "Ruđer Bošković", Zagreb
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
Uključenost u ostale bibliografske baze podataka::
- Chemical Abstracts
