Naslov
Structural study of monoaquabis(pyridine)bis(saccharinato)copper(II), Cu(H2O)(py)2(sac)2

Autori
Jovanovski, Gligor ; Naumov, Panče ; Grupče, Orhideja ; Kaitner, Branko

Izvornik
European journal of solid state and inorganic chemistry (0992-4361) 35 (1998), 3; 231-242

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
copper; saccharinate; X-ray structure; FT infrared spectra

Sažetak
The structure of monoaquabis(pyridine)bis(saccharinato)copper(II), Cu(H2O)(py)2(sac)2, has been investigated by X-ray diffraction and infrared spectroscopy. The complex crystallizes in the orthorhombic space group Iba2 with the following unit cell parameters: a = 9.4874(7), b = 21.545(1), c = 13.164(1) A, V = 2690.8(4) A3, Dc = 1.491 gcm-3, Z = 4, R = 0.025, wR = 0.036. The structure consists of individual Cu(H2O)(py)2(sac)2 molecules. The copper atom is bonded to two pyridine and two saccharinato nitrogen atoms as well as to the water oxygen atom forming a distorted square pyramid. The copper atom lying on a two-fold rotation axis is 0.2209(7) A above the basis square plane formed by the four nitrogen atoms. The bond distances in the coodination polyhedron are: Cu-N11 2.032(2) A, Cu-N21 2.040(2) A, Cu-OW1 2.177(2) A. The N-Cu-N angles amount 88.67(8) and 89.97(8)o as well as 167.36(9) and 167.69(8)o, while the values of the OW1-Cu-N angles are 96.16(6) and 96.32(6)o. The Ft infrared spectral features in the region of the OH, OD, CO and SO2 stretching vibrations are discussed and correlated with the data obtained by X-ray diffraction.

Izvorni jezik
Engleski

Znanstvena područja
Kemija

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