Pregled bibliografske jedinice broj: 322943
Photobehaviour of 2- and 3-heteroaryl substituted o-divinylbenzenes; formation of fused 2,3- and 3,2-heteroareno-benzobicyclo[3.2.1]octadienes and 3-heteroaryl benzobicyclo[2.1.1]hexenes
Photobehaviour of 2- and 3-heteroaryl substituted o-divinylbenzenes; formation of fused 2,3- and 3,2-heteroareno-benzobicyclo[3.2.1]octadienes and 3-heteroaryl benzobicyclo[2.1.1]hexenes // Tetrahedron, 64 (2008), 18; 3928-3934 doi:10.1016/j.tet.2008.02.062 (međunarodna recenzija, članak, znanstveni)
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Naslov
Photobehaviour of 2- and 3-heteroaryl substituted o-divinylbenzenes; formation of fused 2,3- and 3,2-heteroareno-benzobicyclo[3.2.1]octadienes and 3-heteroaryl benzobicyclo[2.1.1]hexenes
Autori
Vidaković, Dragana ; Škorić, Irena ; Horvat, Margareta ; Marinić, Željko ; Šindler-Kulyk, Marija
Izvornik
Tetrahedron (0040-4020) 64
(2008), 18;
3928-3934
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
oxygen heterocycles ; sulfur heterocycles ; furan ; thiophene ; photochemistry ; photocycloaddition ; synthesis
Sažetak
New beta-3-thienyl (8) and beta-3-furyl derivatives of o-divinylbenzene (9) have been synthesized and their photochemical behaviour compared with 2-thienyl (7) and 2-furyl derivatives (2). Whereas the beta-(2-heteroaryl) substituted o-divinylbenzenes (7 or 2) give only bicyclo[3.2.1]octadiene structure (14 or 1) by 1, 6-ring closure of the biradical intermediate, beta-(3-heteroaryl) substituted o-divinylbenzenes (8 or 9) give bicyclo[3.2.1]octadiene structure (23 or 24) and bicyclo[2.1.1]hexene structure (25 or 26) by 1, 6- and 1, 4-ring closure, respectively. This photochemical approach provides a simple method to 2, 3- and 3, 2-fused thiophene and furan polycyclic compounds.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Projekti:
MZOS-125-0982933-2926 - Heteropolicikli, strukturne osnove za bioaktivne spojeve. Sinteza i fotokemija (Škorić, Irena, MZOS ) ( CroRIS)
MZOS-098-0982929-2917 - Spektroskopija NMR i modeliranje bioaktivnih molekula (Plavšić, Dejan, MZOS ) ( CroRIS)
Ustanove:
Institut "Ruđer Bošković", Zagreb,
Fakultet kemijskog inženjerstva i tehnologije, Zagreb
Profili:
Dragana Vuk
(autor)
Željko Marinić
(autor)
Irena Škorić
(autor)
Margareta Sohora
(autor)
Marija Šindler
(autor)
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
- MEDLINE
Uključenost u ostale bibliografske baze podataka::
- CA Search (Chemical Abstracts)