Naslov
EPR Spectra of Copper(II) Complexes with N, N-Dialkyl Amino Acids - the Influence of Water Dissolved in Organic Solvents on the Copper(II) Coordination Sphere

Autori
Noethig Laslo, Vesna ; Paulić, Nevenka

Izvornik
Zeitschrift für anorganische und allgemeine Chemie (0044-2313) 621 (1995), 1; 84-88

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
copper(II) complexes ; EPR spectra

Sažetak
EPR spectra of four bis(N, N-dialkyl-L--aminoacidato) copper(II) complexes were studied with the aim to determine the effect of the water molecules dissolved in organic solvents on the electronic states of copper(II). It was shown that water dissolved in methylene chloride or dioxan influence the copper(II) electronic states. If the amino acid side chains are long enough to form the aliphatic intramolecular van der Waals contacts, the water molecules will induce the change in the conformation of the whole complex.

Izvorni jezik
Engleski

Znanstvena područja
Fizika

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