Pregled bibliografske jedinice broj: 316642
Synthesis, structure and ESR spectrum of (Hmorph)6[VIV, VV, Mo10)VO40] · 3H2O
Synthesis, structure and ESR spectrum of (Hmorph)6[VIV, VV, Mo10)VO40] · 3H2O // Polyhedron, 14 (1995), 8; 1045-1049 doi:10.1016/0277-5387(94)00345-F (međunarodna recenzija, članak, znanstveni)
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Naslov
Synthesis, structure and ESR spectrum of (Hmorph)6[VIV, VV, Mo10)VO40] · 3H2O
Autori
Cindrić, Marina ; Kamenar, Boris ; Strukan, Neven ; Veksli, Zorica
Izvornik
Polyhedron (0277-5387) 14
(1995), 8;
1045-1049
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
vanadium ; heteropoly
Sažetak
The title compound has been synthesized from molybdenum(VI) oxide and ammonium vanadate in aqueous solution by adding morpholine (pH 5.8). The X-ray structural investigation shows that the polyoxometalate anion adopts a Keggin-type structure with a central tetrahedral vanadium (V) atom. The other two vanadium atoms are crystallographically disordered over 12MO(6) octahedral sites. The ESR spectrum clearly indicates that one octahedrally coordinated vanadium atom has the oxidation number +4.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Projekti:
1-07-067
Ustanove:
Institut "Ruđer Bošković", Zagreb,
Prirodoslovno-matematički fakultet, Zagreb
Citiraj ovu publikaciju:
Časopis indeksira:
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
