Naslov
Effect of EPDM on Morphology, Mechanical Properties, Crystallization Behavior and Viscoelastic Properties of iPP+HDPE Blends

Autori
Vranješ, Nina ; Rek, Vesna

Izvornik
Macromolecular Symposia (1022-1360) 258 (2007), 1; 90-100

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
Differential Scanning Calorimetry (DSC); EPDM; Mechanical Properties; Morphology; PP+HDPE Blends

Sažetak
Blends of isotactic polypropylene (iPP) and high density polyethylene (HDPE) with and without ethylene-propylene-diene (EPDM) terpolymer as compatibilizer were systematically investigated to determine the influence of the EPDM on blends properties. The morphology was studied by Scanning Electron Microscopy (SEM). Mechanical properties of investigated systems: tensile strength at break, elongation at break, yield stress and Izod impact strength were determined. Crystallization behavior was determined by Differential Scanning Calorimetry (DSC). Dynamic Mechanical Analysis (DMA) was used to determined the storage modulus (E‘ ), loss modulus (E‘ ‘ ), and loss tangent (tan δ ). The PP+HDPE blend revealed poor adhesion between PP and HDPE phases. Finer morphology was obtained by EPDM addition in PP+HDPE blends and better interfacial adhesion. Addition of HDPE to PP decreased tensile strength at break, elongation and yield stress. Decrease of tensile strength and yield stress is faster with EPDM addition in PP+HDPE blends. Elongation at break and impact strength was significantly increased with EPDM addition. The addition of EPDM in PP+HDPE blends did not significantly change melting points of PP phase, while melting points of HDPE phase was slightly decreased in PP+HDPE+EPDM blends. The EPDM addition increased the percentage of crystallization (Xc) of PP in PP+HDPE blends. The increase of Xc of HDPE was found in the blend with HDPE as matrix. Dynamical mechanical analysis showed glass transitions of PP and HDPE phase, as well as the relaxation transitions of their crystalline phase. By addition of EPDM glass transitions (Tg) of HDPE and PP phases in PP+HDPE blends decreased. Storage modulus (E‘ ) vs. temperatures (T) curves are in the region between E‘ /T curves of neat PP and HDPE. The decrease of E‘ values at 25 °C with EPDM addition in PP+HDPE blends is more pronounced.

Izvorni jezik
Engleski

Znanstvena područja
Kemijsko inženjerstvo

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