Pregled bibliografske jedinice broj: 309227
Theory of reversible electrode reaction coupled to ion transfer across the aqueous electrolyte / ionic liquid interface
Theory of reversible electrode reaction coupled to ion transfer across the aqueous electrolyte / ionic liquid interface // Journal of Solid State Electrochemistry, 12 (2008), 1; 41-45 (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 309227 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Theory of reversible electrode reaction coupled to ion transfer across the aqueous electrolyte / ionic liquid interface
Autori
Lovrić, Milivoj ; Komorsky-Lovrić, Šebojka ; Scholz, Fritz
Izvornik
Journal of Solid State Electrochemistry (1432-8488) 12
(2008), 1;
41-45
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
liquid / liquid interface; ionic liquid; coupled electron and ion transfers
Sažetak
A reversible electro-oxidation of a neutral redox probe dissolved in the room temperature ionic liquid, which is interposed between an electrode surface and an aqueous solution as a thin film, is analyzed theoretically. If the peak potentials in cyclic voltammetry depend on the bulk concentration of electrolyte in water, the oxidation is most probably coupled to the transfer of anions from water into ionic liquid, but if the peak potentials are independent of the electrolyte concentration, the transfers of anions from water into ionic liquid and cations from ionic liquid into water are equally probable.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Projekti:
098-0982904-2907 - Elektroanalitička istraživanja mikrokristala i tragova otopljenih supstanci (Lovrić, Milivoj, MZOS ) ( CroRIS)
Ustanove:
Institut "Ruđer Bošković", Zagreb
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
