2D and 3D supramolecular assemblies of double cyclopalladated azobenzenes realized by C-H center dot center dot center dot Cl-Pd, pi center dot center dot center dot pi and C-H center dot center dot center dot pi interactions

Molčanov, Krešimir; Ćurić, Manda; Babić, Darko; Kojić-Prodić, Biserka

doi:10.1016/j.jorganchem.2007.05.037

Pregled bibliografske jedinice broj: 305804

2D and 3D supramolecular assemblies of double cyclopalladated azobenzenes realized by C-H center dot center dot center dot Cl-Pd, pi center dot center dot center dot pi and C-H center dot center dot center dot pi interactions

Molčanov, Krešimir; Ćurić, Manda; Babić, Darko; Kojić-Prodić, Biserka

2D and 3D supramolecular assemblies of double cyclopalladated azobenzenes realized by C-H center dot center dot center dot Cl-Pd, pi center dot center dot center dot pi and C-H center dot center dot center dot pi interactions // Journal of Organometallic Chemistry, 692 (2007), 18; 3874-3881 doi:10.1016/j.jorganchem.2007.05.037 (međunarodna recenzija, članak, znanstveni)

CROSBI ID: 305804 Za ispravke kontaktirajte CROSBI podršku putem web obrasca

Naslov
2D and 3D supramolecular assemblies of double cyclopalladated azobenzenes realized by C-H center dot center dot center dot Cl-Pd, pi center dot center dot center dot pi and C-H center dot center dot center dot pi interactions
(2D and 3D supramolecular assemblies of double cyclopalladated azobenzenes realized by C-H...Cl-Pd, π • • • π and C-H• • • π interactions)

Autori
Molčanov, Krešimir ; Ćurić, Manda ; Babić, Darko ; Kojić-Prodić, Biserka

Izvornik
Journal of Organometallic Chemistry (0022-328X) 692 (2007), 18; 3874-3881

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
palladium ; azobenzenes ; double cyclopalladation ; X-ray structure ; supramolecular assemblies

Sažetak
The double cyclopalladated complex with azobenzene, μ -[(E)-1, 2-diphenyldiazene-C2, 8, N1, 2]-di-[chloro(dimethylsulfoxide)palladium(II)] ; (DMSO)PdCl(μ -C6H4NNC6H4)(DMSO)PdCl (1) and its analogous complex with DMF as ancillary ligand, (DMF)PdCl(μ -C6H4NNC6H4)(DMF)PdCl ; μ -[(E)-1, 2-diphenyldiazene-C2, 8, N1, 2]-di-[chloro(dimethylformamide)palladium(II)] (2a) were synthesized and the function of cyclopalladated moiety in molecular assembling in the solid state is illustrated by their crystal packings. The polymorphism of 2a and 2b is discussed. The crystal structures reveal assemblies with molecular components self-organized by C– HCl– Pd hydrogen bonds, π π , and C– Hπ interactions. The double cyclopalladated complexes of azobenzene, with two Pd– Cl moieties participating in the hydrogen bond formation and π -conjugated system involved in the π π or C– Hπ interactions, represent a new class of building blocks for construction of solid state supramolecular assemblies.

Izvorni jezik
Engleski

Znanstvena područja
Kemija

POVEZANOST RADA

Projekti:
098-0982915-2950 - Dizajn, sinteza i svojstva organskih liganada i njihovih metalnih kompleksa (Ćurić, Manda, MZOS ) ( CroRIS)
098-1191344-2943 - Protein-ligand međudjelovanja na atomnoj razini (Luić, Marija, MZOS ) ( CroRIS)

Ustanove:
Institut "Ruđer Bošković", Zagreb

Profili:

Manda Ćurić (autor)