Pregled bibliografske jedinice broj: 300040
Electronic structure of metal b-diketonato complexes
Electronic structure of metal b-diketonato complexes // MATH/CHEM/COMP 2007, Book of abstracts / Graovac, Ante ; Pokrić, Biserka ; Smrečki, Vilko (ur.).
Dubrovnik: Interuniverzitetski centar Dubrovnik (IUC), 2007. str. 50-50 (poster, nije recenziran, sažetak, znanstveni)
CROSBI ID: 300040 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Electronic structure of metal b-diketonato complexes
Autori
Novak, Igor ; Kovač, Branka
Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni
Izvornik
MATH/CHEM/COMP 2007, Book of abstracts
/ Graovac, Ante ; Pokrić, Biserka ; Smrečki, Vilko - Dubrovnik : Interuniverzitetski centar Dubrovnik (IUC), 2007, 50-50
ISBN
978-953-6954-26-1
Skup
MATH/CHEM/COMP 2007
Mjesto i datum
Dubrovnik, Hrvatska, 11.06.2007. - 16.06.2007
Vrsta sudjelovanja
Poster
Vrsta recenzije
Nije recenziran
Ključne riječi
_
Sažetak
The electronic structures of yttrium(III), gadolinium(III) and ytterbium(III) tris-2, 2, 6, 6-tetramethyl-3, 5-heptanedione (tmhd) complexes have been investigated by HeI and HeII uv-photoelectron spectroscopy (UPS), UDFT and OVGF calculations. Metal-ligand bonding in the series of metal β -diketonato complexes is discussed on the basis of empirical arguments. When UPS spectra are measured at several photon energies the changes in relative band intensities provide reliable insight into the nature of valence orbital ionizations. The photoionization cross-sections and orbital energies of metal atoms must both be taken into account in order to rationalize changes in relative band intensities of the HeI/HeII spectra.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Projekti:
098-0982915-2945 - Spektroskopija, kemijska svojstva i reakcije biološki aktivnih molekula (Kovač, Branka, MZOS ) ( CroRIS)
Ustanove:
Institut "Ruđer Bošković", Zagreb
