Pregled bibliografske jedinice broj: 296632
Photoelectron Spectroscopy of Metal β -Diketonato Complexes
Photoelectron Spectroscopy of Metal β -Diketonato Complexes // Journal of Organometallic Chemistry, 692 (2007), 11; 2299-2305 doi:10.1016/j.jorganchem.2007.01.061 (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 296632 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Photoelectron Spectroscopy of Metal β -Diketonato Complexes
Autori
Novak, Igor ; Kovač, Branka
Izvornik
Journal of Organometallic Chemistry (0022-328X) 692
(2007), 11;
2299-2305
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
photoelectron spectroscopy; metal diketonates
Sažetak
The electronic structures of yttrium(III), gadolinium(III) and ytterbium(III) tris-2, 2, 6, 6-tetramethyl-3, 5-heptanedione (tmhd) complexes have been investigated by HeI and HeII photoelectron spectroscopy (UPS), UDFT and OVGF calculations. We discuss metal-ligand bonding in the series of metal b-diketonato complexes on the basis of empirical arguments. The photoionization cross-sections and orbital energies of metal atoms must both be taken into account in order to rationalize changes in relative band intensities of the HeI/HeII spectra.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Projekti:
098-0982915-2945 - Spektroskopija, kemijska svojstva i reakcije biološki aktivnih molekula (Kovač, Branka, MZOS ) ( CroRIS)
Ustanove:
Institut "Ruđer Bošković", Zagreb
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
