Pregled bibliografske jedinice broj: 296461
Enantiomers of Sterically Hindered N-aril-4-Pyridones. Cromatographic Enrichment and Thermal Interconversion
Enantiomers of Sterically Hindered N-aril-4-Pyridones. Cromatographic Enrichment and Thermal Interconversion // VIII Sastanak kemičara Hrvatske
Zagreb, Hrvatska, 1983. (poster, nije recenziran, sažetak, znanstveni)
CROSBI ID: 296461 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Enantiomers of Sterically Hindered N-aril-4-Pyridones. Cromatographic Enrichment and Thermal Interconversion
Autori
Mintas, Mladen ; Orhanović, Zlata ; Jakopčić, Krešimir ; Koller, Hans ; Stühler, Georgine ; Mannschreck, Albrecht
Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni
Skup
VIII Sastanak kemičara Hrvatske
Mjesto i datum
Zagreb, Hrvatska, 14.02.1983. - 16.02.1983
Vrsta sudjelovanja
Poster
Vrsta recenzije
Nije recenziran
Ključne riječi
sinteza; prokiralni i kiralni derivati N-aril-4-pirona
(enantiomers; sterically hindered N-aril-4-pyridones)
Sažetak
N-Aryl-4-pyridones l-6 were synthesized by condensation of the corresponding 4-pyrone with anilines. The enrichment of the enantiomers was achieved by liquid chromatography on triacetylcellulose, enantiomeric purities of ( +)– l and (+)– 2 being measured by 1H NMR in the presence of an optically active auxiliary. Barriers to partial rotation about the C- N bond in l-4 were determined and compared with corresponding biphenyls.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Ustanove:
Fakultet kemijskog inženjerstva i tehnologije, Zagreb
