Naslov
Synthesis and [4+4] Photodimerization of 9-trifluoromethylAntracene

Autori
Mintas, Mladen ; Güsten, Hans ; Williard, Paul

Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni

Skup
XII IUPAC Symposium on Photochemistry

Mjesto i datum
Bologna, Italija, 17.07.1988. - 22.07.1988

Vrsta sudjelovanja
Poster

Vrsta recenzije
Nije recenziran

Ključne riječi
sinteza; 4+4 fotodimerizacija 9-trifluormetil anthracena
(synthesis; [4+4] photodimerization of 9-trifluoromethyl antracene)

Sažetak
Trifluoromethylation of 9-iodoanthracene with sodium trifluoroacetate and copper (I) iodide in dipolar aprotic solvent gives 9-trifluoromethylanhracene (TFMA). UV irradiation of TFMA through Pyrex leads to the formation of an anti-[4+4] dimer whose structure was determined by 1H - and 13C-NMR spectroscopy, and confirmed by X-ray crystallography.

Izvorni jezik
Engleski

Znanstvena područja
Kemija

POVEZANOST RADA