Naslov
Chemical pressure-induced ferromagnetism and stabilization of the metallic state in Ba1-xSrxVS3

Autori
Gauzzi, A. ; Licci, F. ; Barišić, Neven ; Calestani, G.L. ; Bolzoni, F. ; Gilioli, E. ; Marezio, M. ; Sanna, A. ; Franchini, C. ; Forro, Laszlo

Izvornik
International journal of modern physics B (0217-9792) 17 (2003), 18/20; 3503-3508

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, kongresno priopćenje, znanstveni

Ključne riječi
metal-insulator transition; chemical pressure effects; magnetic properties

Sažetak
Measurements of magnetization and of resistivity under pressure on Ba1-xSrxVS3 single crystals show that Sr-induced chemical pressure progressively weakens the antiferromagnetic correlations responsible for the metal-insulator transition. The antiferromagnetic ordering temperature, TX = 30 K at x = 0, vanishes at x = 0.08. At larger x, a ferromagnetic order appears with TC = 21.5 K at x = 0.18. The key-parameter favoring the metallic state is found to be the compression of the VS6 octahedra and we predict a metallic state at 0 K for a V– S distance of 2.33 Å ; ; . The stabilization effect of the metallic state provided by the chemical pressure is supported by first principles band structure calculations performed by using the Vienna ab initio simulation package (VASP) within the projector augmented– wave (PAW) method in the local density approximation (LDA) + U scheme.

Izvorni jezik
Engleski

Znanstvena područja
Fizika

Napomena
Rad je prezentiran na skupu Fourth International Conference on New Theories, Discoveries and Applications of Superconductors and Related Materials (New3 SC-4).

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