Pregled bibliografske jedinice broj: 263245
Use of a 9, 10-dihydrofulvalene pincer cycloadduct as a cornerstone for molecular architecture
Use of a 9, 10-dihydrofulvalene pincer cycloadduct as a cornerstone for molecular architecture // Australian Journal of Chemistry, 59 (2006), 12; 899-914 (međunarodna recenzija, članak, znanstveni)
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Naslov
Use of a 9, 10-dihydrofulvalene pincer cycloadduct as a cornerstone for molecular architecture
Autori
Golić, Mirta ; Johnston, Martin R. ; Margetić, Davor ; Schultz, Austin, C. ; Warrener, Ronald N.
Izvornik
Australian Journal of Chemistry (0004-9425) 59
(2006), 12;
899-914
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
polycyclic compounds; cycloaddition; norbornene
Sažetak
Dimethyl-3, 3a, 3b, 4, 6a, 7a-hexahydro-3, 4, 7-metheno-7H-cyclopenta[a] pentalene-7, 8-dicarboxylate (3, a 9, 10-dihydrofulvalene pincer cycloadduct) was found to be a versatile building block for the synthesis of polynorbornyl scaffolds containing various end functionalities such as porphyrins, pyrimidine, and the phenanthroline ligand in the free and complexed forms. The block is stable under various cycloaddition reaction conditions and has high ?-bond reactivity. Molecular modelling using a semi-empirical based method (AM1) shows that incorporation of this diene block into polynorbornyl systems has an important influence on their overall architecture. In particular, incorporation of the block results in a straightening of the curvature normally observed in polynorbornyl molecules to form almost ideally linear polycyclic rigid spacers.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
Uključenost u ostale bibliografske baze podataka::
- Chemical Abstracts
