Naslov
Doubly Cyclopalladated Complexes of Azobenzenes

Autori
Ćurić, Manda ; Babić, Darko ; Molčanov, Krešimir ; Ilz, Gregor ; Plavec, Janez

Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni

Izvornik
Frontiers of biomolecular NMR : inauguration of the 800 MHz NMR spectrometer, ten years of Slovenian NMR Centre : program and book of abstracts / Makuc, Damjan ; Plavec, Janez - Ljubljana : NMR Centre, National Institute of Chemistry, 2006, 54-54

ISBN
961-6104-08-X

Skup
Frontiers of biomolecular NMR : inauguration of the 800 MHz NMR spectrometer, ten years of Slovenian NMR Centre

Mjesto i datum
Ljubljana, Slovenija, 30.06.2006. - 01.07.2006

Vrsta sudjelovanja
Poster

Vrsta recenzije
Nije recenziran

Ključne riječi
reactions; cyclopalladation; azobenzenes; dynamics; NMR

Sažetak
Since the first report, in 1965, describing cyclopalladation of azobenzene1, such reactions have attracted considerable attention by a number of research groups. Palladacycles have been proven useful in organic synthesis, catalysis, photochemistry and even as bioactive compounds.2-5 Since very little is known about the mechanism and reaction dynamics of cyclopalladation reaction with azobenzenes, we have studied the dynamics of formation of doubly cyclopalladated species in dmf. The new insight into the mechanism of cyclopalladation reaction of azobenzenes and reactivity of all involved species in cyclopalladation reaction will enable rational design of the compounds with desired properties.

Izvorni jezik
Engleski

Znanstvena područja
Kemija

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