Pregled bibliografske jedinice broj: 260775
Reactions of the aquapentacyanoferrate(II) ion with 2-nitroso-1-naphthol and 2-nitroso-1-naphthol-4-sulphonic acid
Reactions of the aquapentacyanoferrate(II) ion with 2-nitroso-1-naphthol and 2-nitroso-1-naphthol-4-sulphonic acid // Polyhedron, 14 (1995), 5; 605-609 doi:10.1016/0277-5387(94)00280-R (međunarodna recenzija, članak, znanstveni)
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Naslov
Reactions of the aquapentacyanoferrate(II) ion with 2-nitroso-1-naphthol and 2-nitroso-1-naphthol-4-sulphonic acid
Autori
Foretić, Blaženka ; Burger, Nicoletta ; Hankonyi, Vladimira
Izvornik
Polyhedron (0277-5387) 14
(1995), 5;
605-609
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
UV-VIS and IR spectroscopy ; cyanoferrate(II) complexes ; 2-nitroso-1-naphthol ; quinone oxime
Sažetak
The aqua ligand of the aquapentacyanoferrate(II) ion was replaced by 2-nitroso-1-naphthol and its sulphonate derivative giving the analogous mononuclear nitrosonaphtholpentacyanoferrate(II) complex in the first stage of the reaction. In the second stage, a cyano-bridged binuclear product was obtained and characterized as pentacyanoferrate(II)-mu-cyano-tricyanonitrosonaphtholferrate(II). The latter reaction was catalysed by mercury(II) ions. The complexes were characterized in the basis of analytical, IR and UV-vis spectral data and have in the solid state and in solution a predominately quinone oximic structure. The preparation of the tris(2-nitroso-1-naphthol)ferrate(II) complex is also reported.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
Citiraj ovu publikaciju:
Časopis indeksira:
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
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- CA Search (Chemical Abstracts)
