Naslov
Synthesis and X-ray Structures of New Macrocyclic Thioethers

Autori
Mlinarić-Majerski, Kata ; Pavlović, Dražen ; Luić, Marija ; Kojić-Prodić, Biserka

Izvornik
Chemische Berichte (0009-2940) 127 (1994); 1327-1329

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
macrocyclic thioethers; adamantane as a building block

Sažetak
4, 6:12, 14-Di(1, 3-adamantano)-1, 9-dithiacyclohexadecane(1), 4, 6:12, 14:20, 22-tri(1, 3-adamanto)-1, 9, 17-tritiacyclotetracosane(2), and 5, 7:14, 16-di(1, 3adamanto)-1, 2, 10, 11-tatratiocyclooctadecane(3) have been obtained by intramolecular cyclization of 1, 3-bis(2-bromethil)adamantane(4) with tio acetamid using a high dilution technique. The reaction is concetration dependent. The crystal structures of 1, 2 and 3 have been determined by sungle crystal x-ray diffraction.

Izvorni jezik
Engleski

Znanstvena područja
Kemija

POVEZANOST RADA