Pregled bibliografske jedinice broj: 258550
Deuterium Isotope Effects on Nuclear Shielding. Cross-Ring Effects in Rigid Cyclic Molecules
Deuterium Isotope Effects on Nuclear Shielding. Cross-Ring Effects in Rigid Cyclic Molecules // Magnetic Resonance in Chemistry, 31 (1993), 10; 903-905 doi:10.1002/mrc.1260311005 (međunarodna recenzija, članak, znanstveni)
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Naslov
Deuterium Isotope Effects on Nuclear Shielding. Cross-Ring Effects in Rigid Cyclic Molecules
Autori
Mlinarić-Majerski, Kata ; Vinković, Vladimir ; Chyall, Leonard J. ; Gassman, Paul G.
Izvornik
Magnetic Resonance in Chemistry (0749-1581) 31
(1993), 10;
903-905
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
13C NMR ; 2-methilene-d_2-adamantane derivatives ; deuterium isotpe shifts
Sažetak
Deuterium isotope effects on 13^C NMR chemical shifts, (2^H/1^H)n delta(13^C), of 2-methylene-d2-adamantane, 4-methylene-d_2-2-adamantanone and 6-methylene-d_2-2-adamantanone are presented. Long-range efects (4delta, 5delta and 6delta) in a range from 5 to -23 ppb were observed. The results for 5delta and 6delta are explained in terms of cross-ring field effects resulting from the change of dipole due to deuterium substitution.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
Uključenost u ostale bibliografske baze podataka::
- Chemical Abstracts
