Pregled bibliografske jedinice broj: 258473
2,4-dimethylmethano-2,4-didehydroadamantane and its reactivity in relation to the unsubstituted analogue
2,4-dimethylmethano-2,4-didehydroadamantane and its reactivity in relation to the unsubstituted analogue // Tetrahedron letters, 32 (1991), 13; 1655-1658 doi:10.1016/S0040-4039(00)74297-3 (međunarodna recenzija, članak, znanstveni)
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Naslov
2,4-dimethylmethano-2,4-didehydroadamantane and its reactivity in relation to the unsubstituted analogue
Autori
Mlinarić-Majerski, Kata ; Šafar-Cvitaš, Dunja ; Majerski, Zdenko
Izvornik
Tetrahedron letters (0040-4039) 32
(1991), 13;
1655-1658
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
gem-dimethyl ; propellane ; unsubstituted analogue ; 2, 4-Dimethylmethano-2, 4-didehydroadamantane
Sažetak
2, 4-Dimethylmethano-2, 4-didehydroadamantane (1) has been prepared and the gem-dimethyl substituent effects of propellane 1 in relation to its unsubstituted analogue 2 were studied. The reactivity of 1 is considerably greater than that of 2 due to higher nucleophilicity of its central bond. However, 1 is thermally more stable than 2.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
Citiraj ovu publikaciju:
Časopis indeksira:
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
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