Pregled bibliografske jedinice broj: 250447
Carbonyl and halocarbonyl complexes of molybdenum and tungsten with oxygen donor ligands
Carbonyl and halocarbonyl complexes of molybdenum and tungsten with oxygen donor ligands // Polyhedron, 9 (1990), 8; 1099-1105 doi:10.1016/S0277-5387(00)81301-7 (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 250447 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Carbonyl and halocarbonyl complexes of molybdenum and tungsten with oxygen donor ligands
Autori
Planinić, Pavica ; Meider, Henrika
Izvornik
Polyhedron (0277-5387) 9
(1990), 8;
1099-1105
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
molybdenum ; tungsten ; carbonyl ; halocarbonyl ; complexes ; phosphine oxides
Sažetak
Halogen oxidation of trisubstituted carbonyl complexes of molybdenum(0) and tungsten(0) containing bis[(diphenylphosphinyl)methyl]phenylphosphine oxide (RPPh) and methylenebis[diphenylphosphine oxide] (MDPO) under controlled conditions afforded diamagnetic, seven-coordinate compounds: [M(CO)_3(RPPh)X_2] and [M(CO)_3(MDPO)X_2], where M = Mo, W and X = Br, I. The reaction of molybdenum and tungsten hexacarbonyls with bis[(diphenylphosphinyl)methyl]ethyl phosphinate (RPOEt) was also investigated. Complexes of the type cis-[M(CO)_4(RPOEt)] were isolated, which by treating with iodine released one molecule of carbon monoxide to give metal(II) derivatives, [M(CO)_3(RPOEt)I_2].
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Ustanove:
Institut "Ruđer Bošković", Zagreb
Citiraj ovu publikaciju:
Časopis indeksira:
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
Uključenost u ostale bibliografske baze podataka::
- CA Search (Chemical Abstracts)
