Pregled bibliografske jedinice broj: 250025
Thermal and spectroscopic study of palladium(II) halide complexes with diethyl quinolylmethylphosphonates (DQMP)
Thermal and spectroscopic study of palladium(II) halide complexes with diethyl quinolylmethylphosphonates (DQMP) // Thermochimica Acta, 189 (1991), 2; 175-183 doi:10.1016/0040-6031(91)87113-B (međunarodna recenzija, članak, znanstveni)
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Naslov
Thermal and spectroscopic study of palladium(II) halide complexes with diethyl quinolylmethylphosphonates (DQMP)
Autori
Tušek-Božić, Ljerka ; Trojko, Rudolf
Izvornik
Thermochimica Acta (0040-6031) 189
(1991), 2;
175-183
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
palladium(II) halide complexes ; thermal study ; quinolylmethylphosphonates ; spectral study
Sažetak
Thermal (DTA, TG) and spectroscopic (IR, UV-VIS) studies of palladium(II) dihalide complexes, Pd(dqmp)2X2, and tetrahalogenopalladium salt complexes, [Hdqmp]2[PdX4] (X = Cl or Br), of diethyl 2- and 8-quinolylmethylphosphonates (2-dqmp and 8-dqmp) have been carried out in order to understand the decomposition of these biologically active compounds. Comparing the thermal behaviour of 2-dqmp and 8-dqmp complexes, great differences were observed, especially between the quinolinium salt complexes. On heating to about 100-degrees-C, the 8-dqmp salt complexes were converted into the corresponding hexahalogenodipalladium salt complexes, [H8-dqmp]2[Pd2X6]. The thermal and spectral properties of all the complexes with respect to their cytostatic activity have been discussed.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Ustanove:
Institut "Ruđer Bošković", Zagreb
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
