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Pregled bibliografske jedinice broj: 237816

New complexes of Mo(V) with Schiff Bases. Crystal structure of butylammonium di-mu-oxo-mu-acetato-bis[(N-butylsalicylideniminato-N, O)oxomolybdenum(V)] benzene, acetic acid solvate

Kahrović, Emira; Molčanov, Krešimir; Tušek-Božić, Ljerka; Kojić-Prodić, Biserka
New complexes of Mo(V) with Schiff Bases. Crystal structure of butylammonium di-mu-oxo-mu-acetato-bis[(N-butylsalicylideniminato-N, O)oxomolybdenum(V)] benzene, acetic acid solvate // Polyhedron, 25 (2006), 2459-2464 doi:10.1016/j.poly.2006.02.008 (međunarodna recenzija, članak, znanstveni)

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Naslov
New complexes of Mo(V) with Schiff Bases. Crystal structure of butylammonium di-mu-oxo-mu-acetato-bis[(N-butylsalicylideniminato-N, O)oxomolybdenum(V)] benzene, acetic acid solvate

Autori
Kahrović, Emira ; Molčanov, Krešimir ; Tušek-Božić, Ljerka ; Kojić-Prodić, Biserka

Izvornik
Polyhedron (0277-5387) 25 (2006); 2459-2464

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
Molybdenum(V) ; Schiff base ; Dinuclear-di-mu-oxo-complexes ; Crystal structure

Sažetak
The synthesis of Mo(V) Schiff base complexes derived from alkylamines and salycilaldehyde are reported. The compounds are characterised by chemical analysis, IR and UV/Vis spectroscopy. The title complex C4H9NH3[Mo2O4(N-C4H9-salim)2OCOCH3] • C6H6• CH3COOH is characterised by X-ray structure analysis. The structure is composed of a di-mu-oxo-mu-acetato-bis[(N-butylsalicylideniminato-N, O)oxomolybdenum(V)] anion, butylammonium cation and two solvent molecules: benzene and acetic acid. The Mo atoms of the dinuclear complex [with Mo-Mo bond of 2.5675(5) Å ; ; ] exhibit the octahedral geometry coordinated by a terminal Mo-Oterminal [<1.681(4)> Å ; ; ], a double Mo-Obridging [<1.940(3)>Å ; ; ], Mo-Oacetato with bridging function exhibiting a significant trans influence [2.325(3) and 2.353(3) Å ; ; ], Mo-Ophenolic [<2.050(3)> Å ; ; ] and azomethine nitrogen from a Schiff base [<2.192 (4)> Å ; ; ].

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA

Projekti:
0098035
0098036

Ustanove:
Institut "Ruđer Bošković", Zagreb

Profili:

Avatar Url Ljerka Tušek-Božić (autor)

Avatar Url Biserka Kojić-Prodić (autor)

Avatar Url Krešimir Molčanov (autor)

Poveznice na cjeloviti tekst rada:

doi www.sciencedirect.com doi.org

Citiraj ovu publikaciju:

Kahrović, Emira; Molčanov, Krešimir; Tušek-Božić, Ljerka; Kojić-Prodić, Biserka
New complexes of Mo(V) with Schiff Bases. Crystal structure of butylammonium di-mu-oxo-mu-acetato-bis[(N-butylsalicylideniminato-N, O)oxomolybdenum(V)] benzene, acetic acid solvate // Polyhedron, 25 (2006), 2459-2464 doi:10.1016/j.poly.2006.02.008 (međunarodna recenzija, članak, znanstveni)
Kahrović, E., Molčanov, K., Tušek-Božić, L. & Kojić-Prodić, B. (2006) New complexes of Mo(V) with Schiff Bases. Crystal structure of butylammonium di-mu-oxo-mu-acetato-bis[(N-butylsalicylideniminato-N, O)oxomolybdenum(V)] benzene, acetic acid solvate. Polyhedron, 25, 2459-2464 doi:10.1016/j.poly.2006.02.008.
@article{article, author = {Kahrovi\'{c}, Emira and Mol\v{c}anov, Kre\v{s}imir and Tu\v{s}ek-Bo\v{z}i\'{c}, Ljerka and Koji\'{c}-Prodi\'{c}, Biserka}, year = {2006}, pages = {2459-2464}, DOI = {10.1016/j.poly.2006.02.008}, keywords = {Molybdenum(V), Schiff base, Dinuclear-di-mu-oxo-complexes, Crystal structure}, journal = {Polyhedron}, doi = {10.1016/j.poly.2006.02.008}, volume = {25}, issn = {0277-5387}, title = {New complexes of Mo(V) with Schiff Bases. Crystal structure of butylammonium di-mu-oxo-mu-acetato-bis[(N-butylsalicylideniminato-N, O)oxomolybdenum(V)] benzene, acetic acid solvate}, keyword = {Molybdenum(V), Schiff base, Dinuclear-di-mu-oxo-complexes, Crystal structure} }
@article{article, author = {Kahrovi\'{c}, Emira and Mol\v{c}anov, Kre\v{s}imir and Tu\v{s}ek-Bo\v{z}i\'{c}, Ljerka and Koji\'{c}-Prodi\'{c}, Biserka}, year = {2006}, pages = {2459-2464}, DOI = {10.1016/j.poly.2006.02.008}, keywords = {Molybdenum(V), Schiff base, Dinuclear-di-mu-oxo-complexes, Crystal structure}, journal = {Polyhedron}, doi = {10.1016/j.poly.2006.02.008}, volume = {25}, issn = {0277-5387}, title = {New complexes of Mo(V) with Schiff Bases. Crystal structure of butylammonium di-mu-oxo-mu-acetato-bis[(N-butylsalicylideniminato-N, O)oxomolybdenum(V)] benzene, acetic acid solvate}, keyword = {Molybdenum(V), Schiff base, Dinuclear-di-mu-oxo-complexes, Crystal structure} }

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus

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  • Chemical Abstracts

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