Naslov
Polymer phase of the tetrakis(dimethylamino)ethylene-C-60 organic ferromagnet

Autori
Garaj, Slaven ; Kambe, T. ; Forro, Laszlo ; Sienkiewicz, A. ; Fujiwara, M. ; Oshima, K.

Izvornik
Physical Review B (1098-0121) 68 (2003);

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
High-pressure ESR; TDAE-C_60 single crystal; magnetic properties; polymeric phase; ferromagnetic phase; phase transition; depolymerization

Sažetak
High-pressure electron spin resonance (ESR)measurements were performed on tetrakis (dimethylamino) ethylene (TDAE)-C_60 single crystals and stability of the polymeric phase was established in the P-T parameter space. At 7 kbar the system undergoes a ferromagnetic to paramagnetic phase transition due to the pressure-induced polymerization. The polymeric phase remains stable after the pressure release. The depolymerization of the pressure-induced phase was observed at a temperature of 520 K, revealing an unexpectedly high thermal stability of the polymer. Below room temperature, the polymeric phase behaves as a simple Curie-type insulator with one unpaired electron spin per chemical formula. The TDAE(+) donor-related unpaired electron spins, formerly ESR silent, become active above a temperature of 320 K, which demonstrates that the magnetic properties are profoundly defined by miniscule reorientation of TDAE molecules.

Izvorni jezik
Engleski

Znanstvena područja
Fizika

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