Naslov
Time-Resolved Profiles in Modulated Polarization Spectroscopy

Autori
Vrančič, Aljoša ; Rupnik, Krešimir ; Klasinc, Leo ; McGlynn, S. P.

Izvornik
Journal of chemical information and computer sciences (0095-2338) 39 (1999); 68-76

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Sažetak
The absorption of a modulated light beam in which the state of the polarization is continuously variable is discussed. It is now possible to measure the average time-dependent profile for the polarization cycle of such a beam, and corresponding theoretical descriptions are needed in order to extract the information contained in it. This work generates such a description. Based on a semiclassical treatment of light/matter interactions, a three-parameter fit function is derived that permits the simultaneous extraction of absorbance, linear dichroism, and circular dischroism from the profile for various types of uniformly oriented, partially oriented, and isotropic materials and combinations of them. The theoretical expressions are used to analyze data for (+)-3-methylcyclopentanone, the results being (1) an increase of the S/N ratio, (2) the simultaneous generation of absorption and dichroism spectra of identical quality, and (3) a description of window adsorbates of the cyclopentanone material. The Jones parameters for the macroscopic description of polarized light interactions with matter are reformulated at the microscopic (i.e., transition moment) level, and an alternative derivation of the Jones matrix is given.

Izvorni jezik
Engleski

Znanstvena područja
Kemija

POVEZANOST RADA