Pregled bibliografske jedinice broj: 199272
Efficient and convenient one-pot synthesis of nitriles from carboxylic acids
Efficient and convenient one-pot synthesis of nitriles from carboxylic acids // The 14th Europen Symposium on Organic Chemistry ESOC14, 04.-08.07.2005, Book of abstracts / Hoikkala, Antti ; Karkola, Sampo (ur.).
Helsinki: University of Helsinki, 2005. str. 175-175 (poster, međunarodna recenzija, sažetak, znanstveni)
CROSBI ID: 199272 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Efficient and convenient one-pot synthesis of nitriles from carboxylic acids
Autori
Mlinarić-Majerski, Kata ; Margeta, Renato ; Veljković, Jelena
Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni
Izvornik
The 14th Europen Symposium on Organic Chemistry ESOC14, 04.-08.07.2005, Book of abstracts
/ Hoikkala, Antti ; Karkola, Sampo - Helsinki : University of Helsinki, 2005, 175-175
Skup
The 14th Europen Symposium on Organic Chemistry ESOC14
Mjesto i datum
Helsinki, Finska, 04.07.2005. - 08.07.2005
Vrsta sudjelovanja
Poster
Vrsta recenzije
Međunarodna recenzija
Ključne riječi
one-pot; nitrile; synthesis
Sažetak
Introduction of a cyano group into a molecule, or transformation of an acid into the corresponding nitrile, is not always a simple procedure. In this connection, a procedure that can be used to convert carboxylic acids into nitriles at very high temperatures or via N-acylurea intermediates by using arylboronic acid and rhenium(VII) oxo complexes as active catalysts has been published. Herein, we present a new, efficient and convenient one-pot procedure for conversion of carboxylic acids into nitriles by their treatment with acetonitrile in presence of conc. sulfuric acid. The general preparative value of this reaction will be presented and the mechanism of the reaction will be discussed.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
