Pregled bibliografske jedinice broj: 194429
Bis(dimethyl sulfoxide-kappa O)bis(1-phenylbutane-1, 3-dionato-kappa O-2, O ')nickel(II)
Bis(dimethyl sulfoxide-kappa O)bis(1-phenylbutane-1, 3-dionato-kappa O-2, O ')nickel(II) // Acta crystallographica. Section E, Structure reports online, 60 (2004), 4; 367-369 doi:10.1107/S1600536804004854 (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 194429 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Bis(dimethyl sulfoxide-kappa O)bis(1-phenylbutane-1, 3-dionato-kappa O-2, O ')nickel(II)
Autori
Meštrović, Ernest ; Halasz, Ivan ; Bučar, Dejan-Krešimir ; Žgela, Marijana
Izvornik
Acta crystallographica. Section E, Structure reports online (1600-5368) 60
(2004), 4;
367-369
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
nickel ; adduct ; dimethyl sulfoxide ; crystal structure
Sažetak
In the reaction of bis(1-phenylbutane-1, 3-dionato)nickel(II) with dimethyl sulfoxide, the adduct bis(dimethyl sulfoxide)bis(1-phenylbutane-1, 3-dionato)nickel(II), [Ni(C10H9O2)2(C2H6OS)2], is formed, in which two dimethyl sulfoxide (DMSO) molecules are coordinated to the Ni atom through their O atoms in a trans arrangement. The compound crystallizes in space group P21/a with the Ni atom lying on a center of inversion. The coordination polyhedron around the Ni atom is a distorted octahedron. The chelate ring deviates slightly from planarity. The Ni-O bond distance to the DMSO O atom is slightly longer than that to the 1-phenyl ; butane-1, 3-dionate ligand. In the crystal structure, two-dimensional frameworks are formed by C-HO interactions.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
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- CA Search (Chemical Abstracts)
