Pregled bibliografske jedinice broj: 1932
On the Effect of 1,2-Disubstitution with Me(3)M (M=Si, Ge, Sn) Groups upon the Electronic Structure of 3,3-Dimethylcyclopropene
On the Effect of 1,2-Disubstitution with Me(3)M (M=Si, Ge, Sn) Groups upon the Electronic Structure of 3,3-Dimethylcyclopropene // Chemische Berichte, 129 (1996), 2; 169-174 (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 1932 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
On the Effect of 1,2-Disubstitution with Me(3)M (M=Si, Ge, Sn) Groups upon the Electronic Structure of 3,3-Dimethylcyclopropene
Autori
Eckert-Maksić, Mirjana ; Elbel, S. ; Stohlmeier, M. ; Untiedt, S. ; DeMeijere, A.
Izvornik
Chemische Berichte (0009-2940) 129
(1996), 2;
169-174
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
Electronic structure; Cyclopropenes; 3;3-dimethyl; Photoionization cross-sections; Photoelectron-spectra; Molecular-structure; Cyclopropene isomerization; Thermal-isomerization; Hyperconjugation; Kinetics; Spectroscopy; Derivatives; Pyrolysis
Sažetak
He(I) PE spectra of a series of 3,3-dimethylcyclopropenes bearing Me(3)Si (1), Me(3)Ge (2), and Me(3)Sn (3) groups in the 1- and 2-positions, as well as the He(II) PE spectra of 1 and 3 were recorded. The changes in the lowest energy ionizations along the series are interpreted in terms of inductive and hyperconjugative interactions. The new compounds were prepared by reaction of lithiated 3,3-dimethylcyclopropene with the corresponding trimethylmetal chlorides.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
