Pregled bibliografske jedinice broj: 190515
Kinetics of electrode reaction coupled to ion transfer across the liquid/liquid interface
Kinetics of electrode reaction coupled to ion transfer across the liquid/liquid interface // Book of Abstracts / Scholz, F. ; Schroder, U. ; Plieth, W. (ur.).
Greifswald: Greifswald University, 2005. str. 39-39 (poster, domaća recenzija, sažetak, znanstveni)
CROSBI ID: 190515 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Kinetics of electrode reaction coupled to ion transfer across the liquid/liquid interface
Autori
Komorsky-Lovrić, Šebojka ; Lovrić, Milivoj
Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni
Izvornik
Book of Abstracts
/ Scholz, F. ; Schroder, U. ; Plieth, W. - Greifswald : Greifswald University, 2005, 39-39
Skup
4th Baltic Conference of electrochemistry
Mjesto i datum
Greifswald, Njemačka, 13.03.2005. - 16.03.2005
Vrsta sudjelovanja
Poster
Vrsta recenzije
Domaća recenzija
Ključne riječi
Cyclic voltammetry; Ion transfer; Electrode kinetics; Liquid / liquid interface; Decamethylferrocene
Sažetak
In the theoretical model it is assumed that a graphite disk electrode is covered by a thin film of the solution of decamethylferrocene (dmfc) and some electrolyte CX in nitrobenzene and immersed in an aqueous solution of the electrolyte MX. Oxidation of dmfc is accompanied by the transfer of anion X- from water into nitrobenzene because it is also assumed that cations dmfc+ and C+ are insoluble in water and cation M+ is insoluble in nitrobenzene. Kinetic parameters of electrode reaction can be determined if the total potential difference across the nitrobenzene / water interface is maintained constant by adding the electrolytes CX and MX in concentrations which are much higher than the initial concentration of dmfc in nitrobenzene.
Izvorni jezik
Engleski
Znanstvena područja
Fizika, Kemija
