Pregled bibliografske jedinice broj: 188630
Synthesis of organometallic compounds under high pressure
Synthesis of organometallic compounds under high pressure // Book of abstracts
Brijuni, 2004. (poster, nije recenziran, sažetak, ostalo)
CROSBI ID: 188630 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Synthesis of organometallic compounds under high pressure
Autori
Eckert-Maksić, Mirjana ; Margetić, Davor ; Kirin, Srećko
Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, ostalo
Izvornik
Book of abstracts
/ - Brijuni, 2004
Skup
NATO ARW Brijuni Conference On Matter Under Extreme Conditions: Exploring Fundamental Problems In Science
Mjesto i datum
Brijuni, Hrvatska, 28.08.2004. - 03.09.2004
Vrsta sudjelovanja
Poster
Vrsta recenzije
Nije recenziran
Ključne riječi
High pressure; cycloadditions; organometallics
Sažetak
High pressure synthesis of novel policyclic structures containing silicon and germanium atoms placed at the bridgehead positions, (organometallic derivatives of bicyclo(2.2.1)hept-2-ene) will be presented. Thus, 1-sila-2, 3, 4, 5-tetraphenyl-1, 1-dimethyl-2, 4-cyclopentadiene, 1-sila-2, 5-diphenyl-1, 1-dimethyl-2, 4-cyclopentadienes and 1-germa-2, 3, 4, 5-tetraphenyl-1, 1-dimethyl-2, 4-cyclopentadiene are used as reactive dienes, which readily undergo [4p+2p] cycloadditions with strained alkenes incorporated in norbornene skeleton (for instance, anti-1, 4:5, 8-diepoxy-1, 4, 5, 8-tetrahydroanthracene was used as a dienophile) to give 7-silanorbornene or 7-germanorbornadiene derivatives.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
