Naslov
Synthesis of novel tricyclononanes

Autori
Kragol, Goran ; Mlinarić-Majerski, Kata

Izvornik
Tetrahedron letters (0040-4039) 38 (1997), 30; 5331-5334

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
cyclopropyl ketones; electron transfer; tricyclononane; tricyclononene

Sažetak
Hitherto unknown tricyclo[4.2.1.0(3, 8)]nonan-5-one (2) was prepared by reductive cleavage of tetracyclo[3.3.1.0(2, 8).0(3, 7)]nonan-9-one (1) with lithium in liquid ammonia or reducting 1 via photochemically induced electron transfer. Tricyclic ketone 2 served as precursor for the synthesis of two novel hydrocarbons, i. e. tricyclo[4.2.1.0(3, 8)]nonane (3) and tricyclo[4.2.1.0(3, 8)]non-4-ene (5).

Izvorni jezik
Engleski

Znanstvena područja
Kemija

POVEZANOST RADA