Pregled bibliografske jedinice broj: 180042
New rearrangements in the tert-amyl cation
New rearrangements in the tert-amyl cation // 13th European Symposium of Organic Chemistry
Cavtat, 2003. str. 123-124 (poster, međunarodna recenzija, sažetak, znanstveni)
CROSBI ID: 180042 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
New rearrangements in the tert-amyl cation
Autori
Vrček, Valerije ; Ljubas, Danijel ; Saunders, Martin ; Kronja, Olga
Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni
Izvornik
13th European Symposium of Organic Chemistry
/ - Cavtat, 2003, 123-124
Skup
13th European Symposium of Organic Chemistry
Mjesto i datum
Cavtat, Hrvatska, 10.09.2003. - 15.09.2003
Vrsta sudjelovanja
Poster
Vrsta recenzije
Međunarodna recenzija
Ključne riječi
carbocation rearrangement; NMR spectroscopy; quantum-chemical calculations
Sažetak
Two rearrangement processes that rapidly interchange chemically different hydrogens have been reported in the stable tert-amyl ion. These two processes do not interchange the two inside carbons with the methyl carbons. However, if the 3-pentyl cation is formed, it could rearrange so as to interchange an inside and an outside carbon atom. To see whether this scrambling process does occur, we labeled a methyl group of tert-amyl with 13C. We report here observing its rearrangement to the inside carbon positions by means of 13C NMR spectroscopy. Quantum chemical calculations (at the MP4/6-31G(d, p)//MP2/6-31G(d, p) level of theory) concerning the pathway are also presented.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
